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The Avrami equation describes how solids transform from one phase (state of matter) to another at constant temperature. It can specifically describe the kinetics of crystallisation, can be applied generally to other changes of phase in materials, like chemical reaction rates, and can even be meaningful in analyses of ecological systems. The equation is also known as the Johnson-Mehl-Avrami-Kolmogorov, or JMAK, equation. The equation was first derived by Kolmogorov in 1937 and popularized by Melvin Avrami in a series of papers published in the Journal of Chemical Physics from 1939 to 1941. ==Transformation kinetics== Transformations are often seen to follow a characteristic s-shaped, or sigmoidal, profile where the transformation rates are low at the beginning and the end of the transformation but rapid in between. The initial slow rate can be attributed to the time required for a significant number of nuclei of the new phase to form and begin growing. During the intermediate period the transformation is rapid as the nuclei grow into particles and consume the old phase while nuclei continue to form in the remaining parent phase. Once the transformation begins to near completion there is little untransformed material for nuclei to form in and the production of new particles begins to slow. Further, the particles already existing begin to touch one another, forming a boundary where growth stops. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Avrami equation」の詳細全文を読む スポンサード リンク
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